Ruthenium-catalysed conversion of 1,4-alkynediols into pyrroles |
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Authors: | Simon J. Pridmore |
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Affiliation: | Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK |
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Abstract: | Various 1,2,5-substituted pyrroles have been synthesised from 1,4-alkynediols using a ruthenium catalysed isomerisation to give the corresponding 1,4-dicarbonyl compounds, which undergo in situ cyclisation to pyrroles in the presence of amine. |
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