A new synthesis of trifluorinated compounds via 1,1-dichloro-1-alkenes in superacid |
| |
| Authors: | Anne-Cé line Cantet,Marie-Paule Jouannetaud |
| |
| Affiliation: | Université de Poitiers, CNRS, Laboratoire ‘Synthèse et Réactivité des Substances Naturelles’ 40, Avenue du Recteur Pineau, F-86022 Poitiers Cedex, France |
| |
| Abstract: | A two step process for converting ketone or aldehyde via 1,1-dichloro-1-alkenes to the corresponding 1,1,1-trifluoroderivatives is described, based on HF addition and chlorine-fluorine exchange under superacidic conditions. |
| |
| Keywords: | Trifluorinated compounds 1,1-Dichloro-1-alkene Superacid HF-SbF5 |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
