A new synthesis of trifluorinated compounds via 1,1-dichloro-1-alkenes in superacid |
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| Authors: | Anne-Céline Cantet Marie-Paule Jouannetaud |
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| Institution: | Université de Poitiers, CNRS, Laboratoire ‘Synthèse et Réactivité des Substances Naturelles’ 40, Avenue du Recteur Pineau, F-86022 Poitiers Cedex, France |
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| Abstract: | A two step process for converting ketone or aldehyde via 1,1-dichloro-1-alkenes to the corresponding 1,1,1-trifluoroderivatives is described, based on HF addition and chlorine-fluorine exchange under superacidic conditions. |
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| Keywords: | Trifluorinated compounds 1 1-Dichloro-1-alkene Superacid HF-SbF5 |
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