Catalytic cyanosilylation of ketones with simple phosphonium salt |
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| Authors: | Xiu Wang |
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| Institution: | Joint Laboratory of Green Synthetic Chemistry, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China |
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| Abstract: | In the presence of 1-5 mol % of benzyltriphenylphosphonium chloride, a wide variety of unconjugated and conjugated, acyclic and cyclic ketones were transformed to their corresponding cyanohydrin silyl ethers in excellent yields. |
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| Keywords: | Organocatalysis Phosphonium salts Cyanation Cyanosilylation Ketones |
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