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Asymmetric enamide hydrogenation using planar-chiral cyrhetrenes
Authors:René T Stemmler
Institution:Institut für Organische Chemie der RWTH Aachen, Landoltweg 1, D-52074 Aachen, Germany
Abstract:The catalytic asymmetric hydrogenation of α-arylenamides using catalysts prepared in situ from Rh(cod)2]BF4 and cyrhetrenyldiphosphines was effective with a range of enamides. The corresponding acetamides were obtained with up to 93% ee.
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