Asymmetric enamide hydrogenation using planar-chiral cyrhetrenes |
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Authors: | René T Stemmler |
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Institution: | Institut für Organische Chemie der RWTH Aachen, Landoltweg 1, D-52074 Aachen, Germany |
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Abstract: | The catalytic asymmetric hydrogenation of α-arylenamides using catalysts prepared in situ from Rh(cod)2]BF4 and cyrhetrenyldiphosphines was effective with a range of enamides. The corresponding acetamides were obtained with up to 93% ee. |
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