An expedient stereoselective synthesis of (Z)- and (E)-allyl iodides from Baylis-Hillman adducts along with selective iodination of benzylic alcohols using the polymethylhydrosiloxane-iodine system |
| |
| Authors: | Biswanath Das Harish Holla Nikhil Chowdhury |
| |
| Affiliation: | a Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad 500 007, India
b Organic Chemistry Research Laboratory, School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Vishnupuri, Nanded 431 606, India |
| |
| Abstract: | A stereoselective method has been developed for the synthesis of (Z)- and (E)-allyl iodides from Baylis-Hillman adducts using polymethylhydrosiloxane (PMHS) and iodine in chloroform at room temperature. In addition, the reagent system has been utilized for the iodination of benzylic alcohols selectively. |
| |
| Keywords: | Baylis-Hillman adduct (Z)- and (E)-Allyl iodides Polymethylhydrosiloxane (PMHS) Iodine Benzylic iodide |
| 本文献已被 ScienceDirect 等数据库收录！ |
