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N-(6-Methyl-2-pyridyl)acrylamide: a case of amide hydrolysis without the assistance of acid or base in the synthesis of water-driven H-bonded polymeric chains |
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| Authors: | Kumaresh Ghosh Tanushree Sen |
| Affiliation: | a Department of Chemistry, University of Kalyani, Kalyani, Nadia 741235, India b Organisch-Chemisches Institut, Universität Münster, Corrensstraße 40, D-48149 Münster, Germany |
| Abstract: | Amide hydrolysis of N-(6-methyl-2-pyridyl)acrylamide without the assistance of either acid or base produces the aminopyridinium carboxylate salt at low or room temperature. The carboxylate ion and the free amine functionalities are cooperatively involved in hydrogen bonding with lattice water to form a new hydrogen-bonded polymeric chain. |
| Keywords: | Hydrogen bonding synthon Amide cleavage Hydrogen-bonded polymeric chain Lattice water 2-Amino-6-methylpyridine |
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