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Studies toward the total synthesis of nakiterpiosin: construction of the CDE ring system by a transannular Diels-Alder strategy |
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| Authors: | Tomonori Ito Hirokazu Arimoto Daisuke Uemura |
| Institution: | a Graduate School of Science, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8602, Japan b Graduate School of Life Sciences, Tohoku University, Tsutsumidori-Amamiyamachi, Aoba, Sendai 981-8555, Japan c Institute for Advanced Research, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8602, Japan |
| Abstract: | The transannular Diels-Alder (TADA) reaction was applied to the synthesis of the CDE ring system of nakiterpiosin (1). Tetracyclic compound 25 may be a key intermediate in the total synthesis of 1. |
| Keywords: | Nakiterpiosin Synthetic study Transannular Diels-Alder reaction |
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