Metal free in situ formation of phthalimide N-oxyl radicals by light-induced homolysis of N-alkoxyphthalimides |
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| Authors: | Marco Lucarini Fiammetta Ferroni Stefano Gardi Gunther Schlingloff |
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| Institution: | a Dipartimento di Chimica Organica ‘A. Mangini’, Università di Bologna, Via S. Giacomo 11, 40126 Bologna, Italy
b CIBA Specialty-Chemicals S.p.A., Via Pila 6/3, 40044 Pontecchio Marconi (BO), Italy |
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| Abstract: | Irradiation of N-triphenylmethyloxy- or N-diphenylmethyloxy phthalimide is reported to result in the formation of phthalimide N-oxyl radical (PINO), which is able to initiate and propagate oxidative radical chain reactions of hydrocarbons. |
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| Keywords: | Oxidation Nitroxide Free radical EPR Catalysis |
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