A ratiometric fluorescent chemosensor, 1,10-phenanthroline-4,7-dione, for anions in aqueous-organic media |
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Authors: | Junzo Hirano |
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Institution: | Graduate School of Pharmaceutical Sciences, Kyushu University, 3-1-1 Maidashi, Higashi-ku, Fukuoka 812-8582, Japan |
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Abstract: | A new fluorescent chemosensor, 1,10-phenanthroline-4,7-dione (1), which is capable of the ratiometric sensing of anions in aqueous MeCN, was developed. Chemosensor 1 recognized an anion via two NH groups in the molecule, and showed a much higher affinity for F− than that of 4-quinolone, which binds to an anion at one NH group of the molecule. Upon binding to F−, the intensity of the emission band ascribed to the complex of 1-F− was drastically enhanced, while the emission intensity of unbound 1 gradually decreased. The changes in these two emission bands enabled the successful ratiometric sensing. |
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Keywords: | Anion chemosensor Fluorescence Ratiometric 4-Quinolone Quantum chemical calculation |
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