2,5-Disubstituted furans from 1,4-alkynediols |
| |
| Authors: | Simon J Pridmore |
| |
| Institution: | Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK |
| |
| Abstract: | 1,4-Alkynediols serve as readily available starting materials for isomerisation to 1,4-diketones, which can be converted in situ into the corresponding furans by acid-catalysed dehydration. A range of 2,5-disubstituted furans was prepared using the ruthenium-based catalyst Ru(PPh3)3(CO)H2 with Xantphos at 1 mol % loading. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
