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Evolution of the dynamic mechanical relaxations during the gel formation
Authors:Dominique Durand  Taco Nicolai  Patrice Lefevre  Frederic Prochazka  Hery Randrianantoandro
Abstract:Static and dynamic properties of a polyurethane system at different stages of the gelation process have been investigated. Shear modulus data were collected over a wide frequency range covering both the α-relaxation and the internal modes relaxations. The evolution of the relaxation spectra in relation with the structural transformation occurring during the growth process is analysed within the percolation model.
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