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Controlled macromolecular synthesis by the nucleophile/lewis acid binary systems |
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| Authors: | Takuzo Aida Daisuke Takeuchi Hiroshi Sugimoto Shohei Inoue |
| Abstract: | Amphiphilic initiator systems consisting of bulky nucleophiles as propagating species and bulky electrophiles (Lewis acids) as monomer activators bring about high-speed living anionic polymerization of polar vinylic and heterocyclic monomers to give narrow molecular weight distribution (MWD) polymers. |
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