Nouveaux Élastomères de polyuréthanes dérivés d'aminoacides |
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Authors: | Laurent Fontaine,Laurent Mé nard,Olivier Cayuela,Jean-Claude Brosse,Gé rard Sennyey,Jean-Pierre Senet |
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Abstract: | Synthesis and characterization of new polyurethane elastomers with rigid blocks derived from aminoacids have been achieved by polycondensation using poly(tetramethylene oxide) (PTMO) as a soft segment. Aminotelechelic oligopeptides or pseudopeptides were used in the hard block, eventually in association with lysine diisocyanate (ethyl 2, 6-diisocyanatohexanoate, LDI). Physicochemical characteristics of the so obtained materials, especially good filmmaking properties, allow their use as biomaterials of reduced toxicity. |
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