Transmetallation of beta-allenyl silanes: efficient synthesis of dienyl chlorostannanes and chlorostibines |
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| Authors: | Lahrech Mokhtar Thibonnet Jérôme Hacini Salih Santelli Maurice Parrain Jean-Luc |
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| Institution: | Laboratoire de Synthèse Organique, Université d'Oran Es-Senia, Oran, Algérie. |
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| Abstract: | The reaction of 1-trimethylsilylbuta-2,3-diene with tin tetrachloride, antimony trichloride or antimony pentachloride gave the corresponding buta-1,3-dien-2-yl halostannane or stibine derivatives; this ligand exchange was extended to other beta-allenylsilanes. |
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