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Palladium catalysed copolymerisation of ethene with alkylacrylates: polar comonomer built into the linear polymer chain
Authors:Drent Eite  van Dijk Rudmer  van Ginkel Roel  van Oort Bart  Pugh Robert I
Institution:Shell Research and Technology Centre, Amsterdam Badhuisweg 3, 1031 CM, Amsterdam, The Netherlands.
Abstract:Copolymerisation of ethene and alkylacrylates is catalysed by palladium modified with di(2-methoxyphenyl)phosphinobenzene-2-sulfonic acid (DOPPBS); a linear polymer is produced in which acrylate units are incorporated into the polyethylene backbone.
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