Novel catalysis of dendrimer-bound Pd(0) complexes: sterically steered allylic amination and the first application for a thermomorphic system |
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| Authors: | Mizugaki Tomoo Murata Makoto Ooe Masahiko Ebitani Kohki Kaneda Kiyotomi |
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| Affiliation: | Department of Chemical Science and Engineering, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan. |
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| Abstract: | Phosphinated dendrimer-bound Pd(0) complex catalysts show high stereoselectivity for allylic amination due to the surface congestion of dendrimers and can be easily recycled without loss of activity under thermomorphic conditions. |
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