Creation of a chain-like cationic iron species in montmorillonite as a highly active heterogeneous catalyst for alkane oxygenations using hydrogen peroxide |
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| Authors: | Ebitani Kohki Ide Masahito Mitsudome Takato Mizugaki Tomoo Kaneda Kiyotomi |
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| Institution: | Department of Chemical Science and Engineering, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan. |
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| Abstract: | A chain-like Fe3+ species containing an Fe-O-Fe unit has been prepared within the interlayer space of a montmorillonite, which showed a very high catalytic activity (turnover frequency 386 h-1 and turnover number 23,200) for the oxidation of cyclohexane with H2O2, affording cyclohexyl hydroperoxide as a major product. |
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