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Spontaneous disproportionation of rhodium(I) bisoxazolinates to rhodium(II)
Authors:Willems Sander T H  Russcher Jaap C  Budzelaar Peter H M  de Bruin Bas  de Gelder René  Smits Jan M M  Gal Anton W
Institution:Department of Inorganic Chemistry, University of Nijmegen, Toernooiveld 1, 6525 ED, Nijmegen, The Netherlands.
Abstract:RhI(t-Bu2-boxate)(C2H4)2] spontaneously disproportionates to the mononuclear RhII(t-Bu2-boxate)2], whereas RhI(Ph2-boxate)(C2H4)2] is stable against disproportionation.
Keywords:
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