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Hydrogen-bonded extended structure of the 1:3 adduct of a C3 symmetric cobalt(III) complex with a tripod-ligand involving three imidazolate groups and hydroquinone or resorcinol
Authors:Nagasato Shigeyuki  Sunatsuki Yukinari  Ohsato Susumu  Kido Takafumi  Matsumoto Naohide  Kojima Masaaki
Institution:Department of Chemistry, Faculty of Science, Kumamoto University, Kurokami 2-39-1, Kumamoto 860-8555, Japan.
Abstract:The assembly reaction arising from hydrogen bonding between a chiral C3 symmetric cobalt(III) complex and a tripod-ligand involving three imidazolate groups tris2-(((2-methylimidazolato-4-yl)methylidene)amino)ethyl]amine]cobalt(III) and either hydroquinone or resorcinol gave the 1:3 adducts, with 3D extended structures showing the template effect of the complex.
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