Evidence of an equilibrium between selenides and osmium(VIII) reagents and selenoxides and osmium(VI) reagents |
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| Authors: | Krief Alain Destree Alexandra Durisotti Virginie Moreau Nicolas Smal Caroline Colaux-Castillo Catherine |
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| Affiliation: | Laboratoire de Chimie Organique de Synthèse, Département de Chimie, Facultés Universitaires Notre-Dame de la Paix, 61 rue de Bruxelles, B-5000 Namur, Belgium. alain.krief@fundp.ac.be |
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| Abstract: | Driving the equilibrium between selenides and osmium(VIII) reagents with selenoxides and osmium(VI) by a subsequent reaction (rearrangement of allyl selenoxides to allyl alcohols or addition of osmium(VIII) species on C=C double bonds) to one side, allows the transformation of methyl geranyl selenides to linalool and of methyl citronellyl selenoxide to 6,7-dihydroxy citronellyl selenide. |
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