A novel ribbon-candy-like supramolecular architecture of cadmium(II)-terephthalate polymer with giant rhombic channels: twofold interpenetration of the 3D 8(2)10-a net |
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| Authors: | Dai Jing-Cao Wu Xin-Tao Fu Zhi-Yong Hu Sheng-Min Du Wen-Xing Cui Chuan-Peng Wu Li-Ming Zhang Han-Hui Sun Rui-Qing |
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| Institution: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China. |
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| Abstract: | The hydrothermal reaction of H2tp (tp = terephthalate), Ph3PCH2Ph]Cl and water with Cd(O2CCH3)(2).2H2O gives rise to a novel ribbon-candy-like supramolecular architecture with twofold interpenetration of an unprecedented 3D 8(2)10-a net formed by polymer (Ph3PCH2Ph]Cd(tp).Cl].2H2O]n containing giant rhombic channels, which displays strong fluorescent emission in the solid state. |
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