Ni-complex-catalysed addition polymerisation of 2-phenyl-1-methylenecylopropane to afford a polymer with cyclopropylidene groups |
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| Authors: | Takeuchi Daisuke Osakada Kohtaro |
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| Institution: | Chemical Resources Laboratory, Tokyo Institute of Technology, 4259, Nagatsuta-cho, Midori-ku, Yokohama, Japan. |
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| Abstract: | pi-Allyl-nickel complexes initiated addition polymerisation of 2-phenyl-1-methylenecyclopropane to give a polymer with three-membered rings; the formed polymer showed a high Tg and negligible thermal decomposition up to 300 degrees C. |
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