The first structurally characterised homoleptic sigma-organotitanium(III) compound |
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| Authors: | Alonso Pablo J Forniés Juan García-Monforte M Angeles Martín Antonio Menjón Babil |
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| Affiliation: | Instituto de Ciencia de Materiales de Aragón, Facultad de Ciencias, Universidad de Zaragoza-C.S.I.C, Pza. S. Francisco s/n, E-50009, Zaragoza, Spain. |
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| Abstract: | The paramagnetic [EPR, S = 1/2, d1; gav = 1.959(2)] organotitanate(III) anion [TiIII(C6Cl5)4] has been found to be a mononuclear species with nearly tetrahedral geometry (X-ray). |
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