Self-assembly of double stranded dinuclear titanium(IV)-Schiff base complexes and formation of intramolecular mu-oxo bridges |
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| Authors: | Rao Maddali L N Houjou Hirohiko Hiratani Kazuhisa |
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| Institution: | Nanoarchitectonics Research Center, National Institute of Advanced Industrial Science and Technology, Tsukuba Central 4, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8562, Japan. |
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| Abstract: | The reaction of titanium isopropoxide with a Schiff base ligand containing an isobutenyl linker leads to double stranded dinuclear titanium(IV)-Schiff base complexes through self-assembly with concomitant formation of intramolecular mu-oxo bridges upon hydrolysis. |
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