Amplification of a cyclic mixed-metalloporphyrin tetramer from a dynamic combinatorial library through orthogonal metal coordination |
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| Authors: | Stulz Eugen Ng Yiu-Fai Scott Sonya M Sanders Jeremy K M |
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| Institution: | University Chemical Laboratory, University of Cambridge, Lensfield Road, Cambridge, UK CB2 1EW. |
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| Abstract: | A cyclic porphyrin tetramer, consisting of two bis-phosphine substituted zinc(II) porphyrin units and two Rh(III)TPP units, is selected and amplified virtually quantitatively from a dynamic combinatorial library using 4,4'-bipy as a scaffold and using orthogonal binding modes. |
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