New layered manganese oxide halides |
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| Authors: | Knee Christopher S Weller Mark T |
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| Affiliation: | Department of Chemistry, University of Southampton, Southampton, UK SO17 1BJ. |
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| Abstract: | The first layered manganese(III) oxide chlorides, Sr2MnO3Cl and Sr4Mn3O8-yCl2, have been synthesised; Sr2MnO3Cl adopts a K2NiF4 type structure with sheets of MnO5 square based pyramids linked through oxygen and separated by SrCl layers; it is the end member of a new family of Ruddlesden-Popper type manganese oxide halides which includes the three-layer member Sr4Mn3O8-yCl2 also reported herein. |
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