Oxygenative cleavage of catechols including protocatechuic acid with molecular oxygen in water catalysed by water-soluble non-heme iron(III) complexes in relevance to catechol dioxygenases |
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| Authors: | Funabiki Takuzo Sugio Daisuke Inui Nobuhiko Maeda Matsutaka Hitomi Yutaka |
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| Affiliation: | Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto 606-8501, Japan. funabiki@scl.kyoto-u.ac.jp |
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| Abstract: | Catechol dioxygenase model oxygenations have been performed for the first time in water by using water-soluble nonheme iron(III) complexes, enabling the oxygenation of protocatechuic acid and other catechols. |
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