Polynitrile-bridged two-dimensional crystal: Eu(III) complex with strong fluorescence emission and NLO property |
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| Authors: | Shi Jing-min Xu Wen Liu Qing-yun Liu Feng-ling Huang Zhen-li Lei Hong Yu Wen-tao Fang Qi |
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| Affiliation: | Department of Chemistry, Shandong Normal University, 250014 Jinan, P.R. China. shijingmin@sina.com |
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| Abstract: | The first polynitrile coordinated lanthanide complex ([Eu(cda)3(H2O)3].H2O) infinity (cda = carbamyldicyanomethanide anion) has been synthesized and the two-dimensional structure coordination polymer exhibits strong fluorescence emission and strong powder second harmonic generation efficiency (16.8 times that of urea). |
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