Cyclohexadiene-trans-diols as versatile starting material in natural product synthesis: short and efficient synthesis of iso-crotepoxide and ent-senepoxide |
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| Authors: | Lorbach Volker Franke Dirk Nieger Martin Müller Michael |
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| Affiliation: | Institute of Biotechnology 2, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany. |
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| Abstract: | ![]()
A new synthesis of ent-senepoxide and iso-crotepoxide starting from microbially produced(+)-trans-2,3-dihydroxy-2,3-dihydrobenzoic acid via regio- and stereoselective epoxidation is described. |
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