Molybdenum alkynyls as alkynyl transfer reagents |
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Authors: | Pérez Julio Riera Lucía Riera Víctor García-Granda Santiago García-Rodríguez Esther Miguel Daniel |
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Institution: | Departamento de Química Orgánica e Inorgánica/I.U.Q.O.E.M, Facultad de Quínica, Universidad de Oviedo-C.S.I.C 33071, Oviedo, Spain. |
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Abstract: | Molybdenum alkynyl complexes Mo(C identical to CR)(eta 3-allyl)(CO)2(phen)] feature long Mo-Calkynyl bond distances and propensity to undergo the cleavage of these bonds, a property that allowed their use as acetylide transfer reagents. |
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