Aurophilicity as a cofactor in crystal engineering. Dicyanoaurate(I) anion as a building block in a novel Co(II)-Au(I) bimetallic assembly |
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| Authors: | Colacio Enrique Lloret Francesc Kivekäs Raikko Ruiz José Suárez-Varela José Sundberg Markku R |
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| Institution: | Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, 18071 Granada, Spain. ecolacio@ugr.es |
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| Abstract: | A 2D grid-shaped cyanide-bridged Co(II)-Au(I) bimetallic coordination polymer, Co(DMF)2(Au(CN)2)2], has been prepared from the Au(CN)2]- building block; sheets associate pair-wise by aurophilic interactions and the compound exhibits zeolite-like properties. |
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