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Temperature-controlled combustion and kinetics of different rank coal samples
Authors:M V Kök
Institution:(1) Department of Petroleum and Natural Gas Engineering, Middle East Technical University, 06531 Ankara, Turkey
Abstract:Differential scanning calorimetry (DSC) and thermogravimetry (TG/DTG) has been used to obtain information on the temperature-controlled combustion characteristics of seventeen coals of different origin from Thrace basin of Turkey. Experiments were performed in air atmosphere up to 600°C at a heating rate of 10°C min-1. The DSC/TG curves clearly demonstrate distinct transitional stages in the entire coal samples studied. Reaction intervals, peak and burn-out temperatures of the coal samples are also determined. Two different kinetic methods known as, Arrhenius and Coats-Redfern, were used to analyze the kinetic data and the results are discussed.
Keywords:differential scanning calorimetry  thermogravimetry  thermal analysis  reaction kinetics  coal  lignite
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