Abstract: | Reactions of carbofunctional organosilicon compounds withN,N-dimethyl-N′-trimethylsilylhydrazine andN,N-dimethyl-N′,N′-bis(trimethylsilyl)hydrazine were studied. The composition and structure of the reaction products were found to be dependent
on the reagent nature and the reaction conditions. 1,4-Dimethylamino-2,2,5,5-tetramethyl-1,4-diaza-2,5-disilacyclohexane,
a first representative of a new type of 2,5-disilapiperazines, was synthesized. A scheme of its formation was proposed.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 169–173, January, 1999. |