Interior aliphatic C-H bond activation on iron(II) N-confused porphyrin through synergistic nitric oxide binding and iron oxidation |
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| Authors: | Ching Wei-Min Hung Chen-Hsiung |
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| Affiliation: | Institute of Chemistry, Academia Sinica, Nankang, Taipei, Taiwan. |
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| Abstract: | Iron oxidation, in conjunction with NO coordination, achieved a C-H bond activation to convert [Fe(II)(HCTPPCH(3))Br] into [Fe(HCTPPCH(2))(NO)](BF(4)) at ambient temperature. The structural data and theoretical calculations confirmed the role of nitric oxide behaving as a π-accepting ligand to assist the C-H bond activation. |
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