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A long-lived photo-induced metastable state of linkage isomerization accompanied with a spin transition
Authors:Sheu Chou-Fu  Shih Che-Hsiu  Sugimoto Kunihisa  Cheng Bing-Ming  Takata Masaki  Wang Yu
Affiliation:Department of Chemistry, National Taiwan University, Taipei, 10617, Taiwan, ROC.
Abstract:In addition to the generally observed LIESST phenomenon, polymorph D of trans-[Fe(II)(abpt)(2)(NCS)(2)] exhibits a long-lived photo-induced metastable state through linkage isomerization accompanied with a spin crossover transition, which is stable up to 108 K.
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