A long-lived photo-induced metastable state of linkage isomerization accompanied with a spin transition |
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Authors: | Sheu Chou-Fu Shih Che-Hsiu Sugimoto Kunihisa Cheng Bing-Ming Takata Masaki Wang Yu |
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Affiliation: | Department of Chemistry, National Taiwan University, Taipei, 10617, Taiwan, ROC. |
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Abstract: | In addition to the generally observed LIESST phenomenon, polymorph D of trans-[Fe(II)(abpt)(2)(NCS)(2)] exhibits a long-lived photo-induced metastable state through linkage isomerization accompanied with a spin crossover transition, which is stable up to 108 K. |
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