稀土超分子配合物研究进展

超分子化学作为"广义上的配位化学",是一个充满活力的领域。基于配位自组装,设计合成具有不同拓扑结构和功能特性的超分子配合物是超分子化学的研究重点。基于稀土元素构筑的超分子配合物不仅丰富了配位超分子体系,也是制备功能性配合物的核心内容。主要从拓扑结构调控、结构修饰和功能特性等方面综述了螺旋、格子、环状和笼状等稀土超分子配合物的最新研究进展,探讨了配体设计在超分子自组装过程中的作用,旨在为稀土超分子化合物的设计与调控提供新思路。

Progress on Rare-Earth Supramolecular Complexes

Supramolecular chemistry, as an "extension of coordination chemistry", is a vigorous field. The design and synthesis of supramolecular complexes with different topologies and functional properties based on coordination self-assembly are one of the emphases of supramolecular chemistry. Constructing rare-earth supramolecular complexes are core content of the synthesis of functional complexes, which also pushes the frontier of supramolecular system. This article reviewed the up-to-date research progress of rare earth supramolecular complexes, such as helixes, grids, rings, and cages, in terms of structural modification and properties. Additionally, the role of ligand design in the assemblies was discussed. We are aiming to provide ideas for the design and modulation of rare-earth supramolecular complexes.