The Stille reaction in the synthesis of carotenoid butenolides: synthesis of 6'-epi-peridinin |
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Authors: | Vaz Belén Alvarez Rosana Brückner Reinhard de Lera Angel R |
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Affiliation: | Departamento de Química Orgánica, Universidade de Vigo, 36200 Vigo, Spain. |
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Abstract: | A new strategy for carotenoid butenolides has been developed that is based in part in halogen-selective Stille cross-coupling of dihalogenated ylidenebutenolide segment 2 and highly functionalized alkenylstannanes. [reaction: see text] |
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