151,153Eu electron paramagnetic resonance in SrMoO4 and determination of signs of spin Hamiltonian parameters at different temperatures

The electron paramagnetic resonance (EPR) spectra of Eu²⁺ impurity centers in SrMoO₄ crystals have been studied in the temperature range of 1.8, 100–300 K. A hyperfine structure has been simulated for ^151,153Eu of different EPR transitions observed experimentally at different temperatures and external magnetic field orientations. A unique set of all parameters of the spin Hamiltonian for the known sign of the hyperfine interaction parameters A _i has been determined. It has been found that the diagonal parameters |b _n ⁰ | of the spin Hamiltonian decrease with increasing temperature; however, the parameter b ₄ ⁴ increases. The results of the study have demonstrated that |b ₂ ⁰ (T)/P ₂ ⁰ (T)| ～ const for ^151,153Eu in this single crystal.