| 液相色谱-离子阱质谱对水华蓝藻提取物中微囊藻毒素的定性研究 |
| |
| 引用本文： | 戴明,谢平,陈隽,梁高道.液相色谱-离子阱质谱对水华蓝藻提取物中微囊藻毒素的定性研究[J].分析科学学报,2009,25(4). |
| |
| 作者姓名： | 戴明 谢平 陈隽 梁高道 |
| |
| 作者单位： | 1. 中国科学院水生生物研究所东湖生态站,湖北武汉,430072;福建省中心检验所,福建福州,350002
2. 中国科学院水生生物研究所东湖生态站,湖北武汉,430072 |
| |
| 基金项目： | 中国科学院知识创新工程方向性项目 |
| |
| 摘 要： | 本文研究了野外蓝藻水华样品甲醇提取物的液相色谱和电喷雾质谱特征图谱,利用电喷雾离子化-串联质谱(ESI-MSn)离子阱技术对特征图谱中主要微囊藻毒素的分子离子峰进行了二级质谱分析,获得相应的子离子质谱图,并对其进行了结构解析,确定了野外蓝藻水华样品中微囊藻毒素种类,为准确鉴定和分析水华蓝藻中微囊藻毒素提供了基础.
|
| 关 键 词： | 微囊藻毒素 液相色谱-离子阱质谱 蓝藻 |
Analysis of Microcystins in the Cyanobacterial Water Bloom Extract by Liquid Chromatography-Ion Trap Tandem Mass Spectrometry |
| |
| DAI Ming,XIE Ping,CHEN Jun,LIANG Gao-dao.Analysis of Microcystins in the Cyanobacterial Water Bloom Extract by Liquid Chromatography-Ion Trap Tandem Mass Spectrometry[J].Journal of Analytical Science,2009,25(4). |
| |
| Authors: | DAI Ming XIE Ping CHEN Jun LIANG Gao-dao |
| |
| Institution: | DAI Ming1,2,XIE Ping1,CHEN Jun1,LIANG Gao-dao1(1.Donghu Experimental Station of Lake Ecosystems,Institute of Hydrobiology,ChineseAcademy of Sciences,Wuhan 430072,2.Fujian Province Central InspectionInstitute,Fuzhou 350002) |
| |
| Abstract: | The characteristic fingerprints of acidified methanol extract of the cyanobacterial water bloom collected from Lake Dianchi in China were studies by electrospray mass spectrometry and Liquid Chromatography(LC),respectively.Mass spectrum and structural elucidation were achieved using ion trap tandem mass spectrometry in the full scan mode.Three structural variants of microcystins have been successfully isolated and identified. |
| |
| Keywords: | Microcystin Liquid chromatography-mass spectrometry Blue-green alge |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
