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ESR study of some iminoxy free radicals generated from phosphorylated oximes and dioximes |
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| Authors: | A V Il’yasov A A Vafina E Breuer G Hägele |
| Institution: | 1. Arbusov Institute of Organic and Physical Chemisry, Kazan, Russian Federation 2. Department of Pharmaceutical Chemistry, Hebrew University of Jerusalem, Jerusalem, Israel 3. Institute of Inorganic and Structure Chemistry, Heinrich-Heine-University of Düsseldorf, Düsseldorf, Germany |
| Abstract: | The new type of phosphoniminoxy free radicals was generated electrochemically or by chemical oxidation of oximes. It was established the strong difference of ESR parameters for isomeric Z and E forms of the radicals. The spin distribution and its correlation with electronic and spatial characteristics of molecules as well as with intramolecular interactions are discussed. |
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