Untersuchungen an Wasseraddukten des Antimon(V)-chlorids

Studies on Water Adducts of Antimony(V) Chloride Antimony(V) chloride gives four solid adducts of sbCl₅ · nH₂O I-IV (n = 1, 2, 3, 4) at room temperature. In the solid state I is oligomer by hydrogen bridges. In II, III, and IV are besides the adducts ionic products of the constitution H⁺(H₂O)_n] SbCl₅OH^? (n = 1, 2, 3). I and II reacts with sodium chloride to yield sodium hexachloroantimonate(V) · 1 resp. 2 H₂O. The vibrational spectra were discussed.