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Beiträge zur Chemie der Übergangsmetall-Diolefinkomplexe. III. Elektrochemische Darstellung von Kobaltkomplexverbindungen acyclischer 1,3-Diolefine
Authors:H.-J. Kerrinnes  U. Langbein
Abstract:Contributions to the Chemistry of Transition Metal Diolefin Complexes. III. Electro-chemical Preparation of Cobalt Complex Compounds of Noncyclic 1,3-Diolefins The synthesis is described of butadiene coordination compounds of the type (π-C4H6)Co(π-C4H6R) · L by electrolytic reduction of cobalt salts in presence of butadiene, where R represents an H or C4H7 radical and L P(n-C4H9)3 or P(C6H5)3.
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