Synthesis of a novel tripodand having 3-hydroxy-2-naphthoeic amide groups and its anion recognition ability |
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| Authors: | Jie Hao Kazuhisa Hiratani Naohiro Kameta Toru Oba |
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| Institution: | 1. Department of Applied Chemistry, Utsunomiya University, 7-1-2 Youtou, Utsunomiya, 321-8585, Japan
2. National Institute of Advanced Industrial Science and Technology, Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, 305-8565, Japan
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| Abstract: | A novel tripodand having 3-hydroxy-2-naphthoeic amide groups was prepared by the reaction of 1,3,5-tris(aminomethyl)-2,4,6-trimethylbenzene with 3-allyloxy-2-naphthoeic acid chloride followed by thermal Claisen rearrangement. This tripodand can exhibit the anion binding ability in chloroform solution. In particular, it can bind with acetate, dihydrogen phosphate, and fluoride ions to form 1:1 complexes. |
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