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Total synthesis of proposed structure of xylogiblactone B by chiron approach
Authors:Palakodety Radha Krishna  Ramesh Kunde  Rajesh Nomula  Kallaganti V.S. Ramakrishna
Affiliation:1. D-211, Discovery Laboratory, Organic & Biomolecular Chemistry Division, CSIR-Indian Institute of Chemical Technology, Hyderabad 500 007, India;2. Center for Nuclear Magnetic Resonance, CSIR-Indian Institute of Chemical Technology, Hyderabad 500 007, India
Abstract:Total synthesis of the proposed structure of xylogiblactone B is described using d-(+)-mannitol, regioselective epoxide ring-opening, Yamaguchi esterification, and ring-closing metathesis as key steps.
Keywords:Polyol γ-lactones   Xylogiblactones   Regioselective epoxide ring-opening   Yamaguchi esterification   Ring-closing metathesis
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