|
|||||
|
|
Titanocene-catalyzed metallation of propargylic acetates in homopropargyl alcohol synthesis |
|
| Authors: | Jennifer L Meloche Peter T VednorJoseph B Gianino Allen G OliverBrandon L Ashfeld |
| Institution: | Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46637, United States |
| Abstract: | The titanium-catalyzed metallation and subsequent carbonyl addition of propargylic acetates enable the direct formation of homopropargylic alcohols in good yields. The corresponding products were obtained as single regioisomers without the corresponding allene adducts observed. |
| Keywords: | Titanocene-catalyzed Propargylic acetates Homopropargyl alcohols Metallation/carbonyl addition |
| 本文献已被 ScienceDirect 等数据库收录！ | |