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Au(I)/Ag(I)-catalyzed annulation of sugar aldehyde tethered with 3-phenylprop-2-yn-1-yl ether with aryl amines for the pyrano[4,3-b]quinoline derivatives
Authors:BV Subba Reddy  Nilanjan Majumder  B Sridhar
Institution:1. Natural Product Chemistry, CSIR-Indian Institute of Chemical Technology, Hyderabad 500 007, India;2. Laboratory of X-ray Crystallography, CSIR-Indian Institute of Chemical Technology, Hyderabad 500 007, India
Abstract:Aryl amines undergo smooth annulation with O-phenylpropynyl sugar aldehyde in the presence of the Ph3PAuCl (10 mol %)/AgSbF6 (10 mol %) catalytic system to afford the corresponding tetrahydro-3aH-spiro1,3]dioxolo4″,5″:4′,5′]furo3′,2′:5,6]pyrano4,3-b]quinoline-2,1′-cyclohexane] derivatives in good yields and selectivity.
Keywords:O-Phenylpropynyl sugar aldehyde  Aryl amines  Au(I) catalysis  Pyrano[4  3-b]quinolines
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