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Total synthesis of catenioblin B |
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| Authors: | Theegala Srinivas Helmut M Hügel Palakodety Radha Krishna |
| Institution: | 1. D-211, Discovery Laboratory, Organic & Biomolecular Chemistry Division, CSIR-Indian Institute of Chemical Technology, Hyderabad 500 007, India;2. RMIT University, School of Applied Science, Melbourne, VIC 300, Australia |
| Abstract: | Herein we report the first total synthesis of catenioblin B (1) via a titanium(IV) mediated regioselective epoxide ring-opening, Grignard reaction, Luche’s reduction and TEMPO/BAIB mediated intramolecular cyclization as the key steps. |
| Keywords: | Catenioblins Pyranone derivative Sharpless epoxidation Regioselective epoxide ring-opening Grignard reaction |
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