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Rhodium catalyzed three-component reaction of aldehyde,boronic acid,and sulfonamides: a facile one-pot synthesis of diarylmethylamines |
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| Authors: | Ponnam Satyanarayana Ganapam Manohar ReddyHariharasarma Maheswaran Mannepalli Lakshmi Kantam |
| Affiliation: | Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
| Abstract: | Rhodium(I) catalyzed three-component reaction for the one pot synthesis of diarylmethylamines in excellent yields were achieved by using aldehyde, boronic acid, and sulfonamides. The use of hyper-valent bis(trifluoroacetoxy)iodobenzene as an additive plays a key role in the chemo selective formation of amines instead of alcohols. |
| Keywords: | Bis(1,5-cyclooctadiene)-rhodium(I)-tetrafluoroborate Diaryl methylamines Bis(trifluoroacetoxy)-iodobenzene Three component reaction Homogeneous catalysis |
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