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Asymmetric ring opening reaction of oxabenzonorbornadienes with amines promoted by iridium/NMDPP complex |
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| Authors: | Lu Yu Yongyun Zhou Xin Xu Sifeng Li Jianbin Xu Baomin Fan Chengyuan Lin Zhaoxiang Bian Albert S.C. Chan |
| Affiliation: | 1. YMU-HKBU Joint Laboratory of Traditional Natural Medicine, Yunnan Minzu University, Kunming 650500, China;2. School of Chinese Medicine, Hong Kong Baptist University, Hong Kong, China;3. Institute of Creativity, Hong Kong Baptist University, Hong Kong, China |
| Abstract: | As an efficient catalyst, the [Ir(COD)Cl]2/NMDPP complex has been successfully applied to promote the asymmetric ring opening reaction of oxabenzonorbornadienes with various amines, which afforded the corresponding products in good yields (72–98%) with good enantioselectivities (80–90% ee). |
| Keywords: | Oxabenzonorbornadienes ARO reaction (S)-NMDPP Amines |
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